Journal
ORGANIC LETTERS
Volume 7, Issue 21, Pages 4617-4620Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol051703u
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- NIGMS NIH HHS [GM61006] Funding Source: Medline
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The annulation reactions of alkenes with peroxycarbenium ions enable the synthesis of a variety of functionalizable 1,2-dioxolanes. Triethysilyl-protected peroxycarbenium ions proved to be optimal for the annulation reaction. Using this method, plakinic acid analogues can be synthesized in three steps from the corresponding ketone and alkene.
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