Journal
ORGANIC LETTERS
Volume 7, Issue 21, Pages 4773-4775Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol052044o
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Bis(dipyrromethene)s with relatively long spacers (>5 atoms) form helical monomeric complexes as the two binding units of the bis(dipyrromethene) chelate around the same tetrahedrally coordinated metal ion. Herein we report the first highly diastereoselective mononuclear helicate-forming complexation reactions of bis(dipyrromethene)s using homochiral binol and tartrate motifs which serve as both linkers and asymmetric templates.
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