Journal
JOURNAL OF APPLIED POLYMER SCIENCE
Volume 98, Issue 2, Pages 869-879Publisher
WILEY
DOI: 10.1002/app.22188
Keywords
microstructure; modeling; nanocomposites; particle size distribution; structure-property relations
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A review of analytical modeling of particulate reinforcement is made as a prelude to the problem of microstructural inhomogeneity in nanocomposite materials. Noting the inevitability of dispersion nonuniformity, and variations in agglomerate morphology and filler-matrix interaction, the need to question the application of such models to novel materials arises. Employing the mechanical properties of alumina/epoxy nanocomposites, with known dispersion characteristics, an evaluation of the predictive capability of various models for Young's modulus, strength, and failure strain is made. Comparison between models is accompanied by a discussion of the parameters used in the fitting of macroscopic behavior to microstructural features. (c) 2005 Wiley Periodicals, Inc.
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