4.7 Article

Spin-crossover cobalt(II) compound with banana-shaped structure

Journal

INORGANIC CHEMISTRY
Volume 44, Issue 21, Pages 7295-7297

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic051059f

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A banana-shaped spin-crossover (SCO) cobalt(II) complex [Co(C16-terpy)(2)](BPh4)(2) (1) with long alkyl chains, based on a terpyricline frame, was synthesized. Compound 1 exhibited very gradual SCO behavior and changes in the dielectric constant. This shows a way in which SCO materials can be used in electronic devices.

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