Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 127, Issue 42, Pages 14655-14662Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja052035a
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Organic/inorganic core shell nanoparticles have been synthesized using high K TiO2 as the core nanoparticle, and polystyrene as the shell. This material is easy to process and forms transparent continuous thin films, which exhibit a dielectric constant enhancement of over 3 times that of bulk polystyrene. This new dielectric material has been incorporated into capacitors and thin film transistors (TFTs). Mobilities approaching 0.2 cm(2)/V (.) s have been measured for pentacene TFTs incorporating the new TiO2 polystyrene nanostructured gate dielectric, indicating good surface properties for pentacene film growth. This novel strategy for generating high K flexible gate dielectrics will be of value in improving organic and flexible electronic device performance.
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