Journal
ORGANIC LETTERS
Volume 7, Issue 22, Pages 4875-4878Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0517271
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[GRAPHICS] Suzuki-Miyaura cross-coupling of benzylic phosphates with arylboronic acids was investigated. Optimum conditions employed the simple catalytic system of palladium(II) acetate (1 mol %) and triphenylphosphine (4 mol %) with either potassium phosphate or potassium carbonate as the base and toluene as the solvent at 90 degrees C. Using the developed conditions, a series of structurally diverse diarylmethanes were prepared.
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