Journal
ORGANIC LETTERS
Volume 7, Issue 22, Pages 4871-4874Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol051615+
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[GRAPHICS] The combination of diethyl phosphite and DMAP as ligands for nickel in an 8:1 THF-N-ethylpyrrolidinone (NEP) mixture allows a very efficient cross-coupling reaction to be performed between various functionalized arylzinc halides and aryl bromides, triflates and activated chlorides. The reaction proceeds at 25 degrees C within 1-48 h and requires only 0.05 mol % of the nickel catalyst.
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