Journal
JOURNAL OF PHYSICAL CHEMISTRY A
Volume 109, Issue 42, Pages 9494-9498Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp053128h
Keywords
-
Ask authors/readers for more resources
The cluster isolated chemical reactions technique is used to examine the dynamics of the photoinduced reaction producing electronically excited CaF when 1:1 (CaCH3F)-C-. complexes are deposited at the surface of large argon clusters. This technique ensures quantitatively that 1: 1 complexes are actually at the origin of the observed signals. The reaction is monitored by observing the CaF chemiluminescence while scanning the photoexcitation laser. The resulting action spectrum contains information about the absorption bands of the complex, filtered by the dynamics of the reaction. The observations suggest a profound alteration of the calcium electronic structure and a control of the reaction by the CF stretch in CH3F.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available