Journal
ORGANIC LETTERS
Volume 7, Issue 22, Pages 4975-4978Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol051929x
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[GRAPHICS] Benzylboranes are noticeably uncommon partners within Suzuki-Miyaura coupling reactions. B-Benzyl-9-BBN was successfully coupled to a range of aryl/heteroaryl bromides, chlorides, and triflates to give pharmacologically important methylene-linked biaryl structures. Activated, deactivated, and sterically hindered substrates were successfully coupled in high yield using Pd(PPh3)(4) or Pd(OAc)(2) with SPhos as the catalyst system.
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