Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 70, Issue 22, Pages 9074-9076Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo051490m
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[GRAPHIC] Metalation of oxazoles at the 4 and 5 position was achieved after regioselective C-2 silyl protection. Removal of the protecting group was then accomplished under mild conditions allowing for a straightforward preparation of C-5 monosubstituted and C-4,5 disubstituted oxazoles. The first practical C-2 protecting group of oxazoles has been demonstrated.
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