4.4 Article

Phase transitions in equilibrium systems: microscopic models and mesoscopic free energies

Journal

MOLECULAR PHYSICS
Volume 103, Issue 21-23, Pages 3141-3151

Publisher

TAYLOR & FRANCIS LTD
DOI: 10.1080/00268970500221990

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We describe the derivation of mesoscopic free energy functionals for systems with long-range Kac potentials and analyse them in the presence of phase transitions. This yields information about the arrangement of phases in some binary mixtures as well as explicit criteria for the stability of liquid droplets in a one-component fluid described by a Cahn-Hilliard type of free energy functional.

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