Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 26, Issue 21, Pages 1687-1692Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200500507
Keywords
covalently bonded; phenylglycine; photoinitiator; photopolymerization; radical polymerization
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Bimolecular type-II photoinitiators for radical photopolymerization suffer from a diffusion-controlled limitation of reactivity and from deactivation by back electron transfer. Here, a very efficient concept to increase the photoinitiator activity by the covalent binding of phenylglycine to benzophenone using a methylene spacer is presented. Photo-DSC experiments proved that the rate of polymerization can be tripled in comparison to a physical mixture of the components or an industrially applied system with triethanolamine as coinitiator.
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