Journal
ADVANCED FUNCTIONAL MATERIALS
Volume 15, Issue 11, Pages 1877-1882Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.200400608
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Liquid crystalline epoxy/polyaniline (LCE/PANI) composite nanowires have been fabricated using an anodic aluminum oxide (AAO) membrane by a temperature-gradient curing process. PANI nanorods with an average diameter of 30 nm have been synthesized by dispersion polymerization in order to employ them as a curing agent for LCE and as a reinforcement filler for the LCE/PANI composite nanowires. Differential scanning calorimetry and Fourier-transform infrared spectroscopy indicate that the LCE crosslinking reaction occurred inside the channels of the AAO membrane via the curing of LCE with PANI nanorods. The LCE/PANI composite nanowires exhibit an enhanced electrical conductivity and thermal stability, comparable with a LCE/PANI composite monolith. In addition, these polymer-composite nanowires also display the characteristics of a functionally gradient conducting material.
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