4.5 Article

Sources of primitive alkaline volcanic rocks from the central European volcanic province (Rhon, Germany) inferred from Hf, Os and Pb isotopes

Journal

CONTRIBUTIONS TO MINERALOGY AND PETROLOGY
Volume 150, Issue 5, Pages 546-559

Publisher

SPRINGER
DOI: 10.1007/s00410-005-0029-4

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Basanites and nephelinites from the Tertiary Rhon area (Germany), which are part of the Central European Volcanic Province (CEVP), have high MgO, Ni and Cr contents and prominent garnet signatures indicating that they represent near-primary magmas formed by melting of a CO2-bearing peridotitic mantle source at high pressure. The Pb and Hf isotope (and previously published Nd and Sr isotope) ratios of the Rhon lavas are rather uniform, whereas the Os isotope composition is highly variable. For the most primitive basanites, Pb, Os and Hf isotope compositions fall within the range of enriched MORB and some OIB. Other basanites and nephelinites with low Os concentrations have distinctly more radiogenic Os (Os-187/Os-188: 0.160 0.469) isotope compositions, which are inferred to originate from crustal contamination. The samples with the highest Os concentrations have the lowest Os isotope ratios (Os-187/Os-188((23 Ma)): 0.132-0.135), and likely remain unaffected by crustal contamination. Together with their fairly depleted Sr, Nd and Hf isotope ratios, the isotopic composition of the Rhon lavas suggests derivation from in asthenosplieric mantle source. Prominent negative K and Rb anomalies, however, argue for melting aniphibole or phlogopite-bearing sources, which call only be stable in the cold lithosphere. We therefore propose that List lien ospheric melts precipitated at the asthenosphere-lithosphere thermal boundary as veins in the lithospheric mantle and were remelted or incorporated after only short storage times (about 10100 million years) by ascending asthenospheric melts. Due to the short residence time incorporation of the vein material imposes the prominent phlogopite/amphibole signature of the Rhon alkaline basalts but does not lead to a Shift ill the isotopic Signatures, Melting of the lithosplieric mantle cannot strictly be excluded, but has to be subordinate due to the lack of the respective isotope signatures. ill good agreement with the fairly thin lithosphere observed in the Rhon area. The fairly radiogenic Pb isotope Signatures Lire expected to originate from inciting of enriched. low melting temperature portions incorporated ill the depleted Lipper (asthenospheric) mantle and therefore do not require upwelling of deep-seated mantle Sources for the Rhon or many other continental alkaline lavas with similar Pb isotope signatures.

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