Journal
COORDINATION CHEMISTRY REVIEWS
Volume 249, Issue 21-22, Pages 2222-2231Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2005.04.008
Keywords
heteropolyacids; MTBE; ETBE synthesis
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Heteropolyacids (HPA) are polyoxometalates exhibiting high activity in the acid-base type of catalytic reaction. This review paper discusses the role of the primary and secondary structure of solid HPAs in the catalytic synthesis of tertiary ethers, MTBE and ETBE, on H4SiW12O40 and H6P2W18O62 catalysts. (c) 2005 Elsevier B.V. All rights reserved.
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