Journal
ADVANCED MATERIALS
Volume 17, Issue 21, Pages 2618-+Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200500502
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Films of a symmetric A-B diblock copolymer and A-coated An nanoparticles cast from a selective solvent for A develop a lamellar surface layer. The surface layers have a low volume fraction of nanoparticles in the A lamellae atop a substrate layer of B cylinders/spheres in an A matrix containing a larger volume fraction of nanoparticles (see Figure). This arrangement thus induces an order-order transition between block-copolymer phases as their concentration is increased.
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