Journal
CHEMISTRY LETTERS
Volume 34, Issue 11, Pages 1560-1561Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2005.1560
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Hydrothermal decomposition experiments of glycerin with an alkali showed that glycerin could be converted into lactic acid with a high yield of about 90 mol % based on glycerin used. Discussion on the pathway for the conversion of glycerin to lactic acid suggests that glycerin is first decomposed to pyruvaldehyde with elimination of hydrogen by a H- shift to the adjacent hydrogen. Pyruvaldehyde formed is then converted into lactic acid ion by the benzilic acid rearrangement.
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