Journal
ORGANIC LETTERS
Volume 7, Issue 23, Pages 5167-5170Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0520020
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- NIGMS NIH HHS [GM 46503] Funding Source: Medline
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Dirhodium caprolactamate [Rh-2(cap)(4)] is an effective catalyst for benzylic oxidation with tert-butyl hydroperoxide (TBHP) under mild conditions. Sodium bicarbonate is the optimal base additive for substrate conversion. Benzylic carbonyl compounds are readily obtained, and a formal synthesis of palmarumycin CP2 using this methodology is described.
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