Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 70, Issue 23, Pages 9595-9598Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo0516180
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Funding
- NIGMS NIH HHS [GM076261] Funding Source: Medline
- NIMH NIH HHS [MH 070040] Funding Source: Medline
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Copper-catalyzed azide alkyne cycloadditions of the linear substrates 1 were used to form the cyclic derivatives 2. Computational, NMR, and CD analyses of these compounds indicate that their most favorable conformational states include type I and type H beta-turn conformations. Selectivity for the dimeric products 6 in these cyclization reactions is discussed.
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