4.4 Article

Metal-free imination of sulfoxides and sulfides

Journal

TETRAHEDRON LETTERS
Volume 46, Issue 46, Pages 8007-8008

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2005.09.070

Keywords

asymmetric synthesis; iminations; metal-free; sulfoxides; sulfoximines

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Using a nitrogen transfer agent obtained in situ by mixing of NsNH(2) and PhI(OAc)(2), various N-nosyl sulfoximines and N-nosyl sulfilimines have been prepared under metal-free conditions starting from the corresponding sulfoxides and sulfides, respectively. (c) 2005 Elsevier Ltd. All rights reserved.

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