4.7 Article

Rare-earth iodides in ionic liquids:: The crystal structure of [SEt3]3[LnI6] (Ln = Nd, Sm)

Journal

INORGANIC CHEMISTRY
Volume 44, Issue 23, Pages 8168-8169

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic051533h

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Crystals of [SEt3](3)[Lnl(6)] (Ln = Nd, Sm) were obtained by the reaction of Lnl(2) with the ionic liquid [SEt3][Tf2N] [Tf2N = bis(trifluoromethanesulfonyl)imide]. The compounds are characterized by octahedral [Lnl(6)](3-) units that are surrounded by a distorted cube of triethylsulfonium cations.

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