Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 690, Issue 23, Pages 5378-5382Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2005.05.018
Keywords
copper catalysts; oxidation; C=C cleavage; molecular oxygen
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A novel C=C bond cleavage reaction of aromatic enol ethers (1) to give ketones (2) using molecular oxygen as oxidant is described. Among the examined catalysts (Cu(II), Pd(II), Ru(II), and H+), CuCl2 exhibited the highest activity. The reaction proceeded smoothly with several kinds of substrates. (c) 2005 Elsevier B.V. All rights reserved.
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