Journal
LANGMUIR
Volume 21, Issue 24, Pages 11425-11430Publisher
AMER CHEMICAL SOC
DOI: 10.1021/la051772h
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A simple method for growing polymer brushes by atom transfer radical polymerization (ATRP) off solid surfaces has been devised. This entails pulsed plasmachemical deposition of a halogen-containing initiator layer, followed by either organic or aqueous phase controlled surface polymerization. The wide-scale applicability of this approach is exemplified by functionalizing flat substrates, microbeads, and nonwoven textiles.
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