Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 123, Issue 20, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.2064947
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New high-resolution infrared and UV/visible spectra of (AgH)-Ag-107, (AgH)-Ag-109, (AgD)-Ag-107, and (AgD)-Ag-109 have been recorded with a Fourier transform spectrometer. The new line positions are combined with published microwave and older electronic A (1)Sigma(+)-X (1)Sigma(+) data and used, first in a decoupled analysis of the X state alone, and then in a global multi-isotopologue analysis which yields comprehensive descriptions of both the X (1)Sigma(+) and A (1)Sigma(+) states of all four isotopologues of AgH. While the A state was long believed to be heavily perturbed, it is shown that its irregular spectrum merely reflects an unusual potential function shape. A direct fit of all data to appropriate radial Hamiltonians yields analytic potential-energy functions and Born-Oppenheimer breakdown radial functions for the ground X (1)Sigma(+) and A (1)Sigma(+) states. (c) 2005 American Institute of Physics.
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