4.5 Article

Variability of Mg/Ca and Sr/Ca between and within the planktonic foraminifers Globigerina bulloides and Globorotalia truncatulinoides -: art. no. Q11D15

Journal

GEOCHEMISTRY GEOPHYSICS GEOSYSTEMS
Volume 6, Issue -, Pages -

Publisher

AMER GEOPHYSICAL UNION
DOI: 10.1029/2004GC000811

Keywords

electron microprobe; Mg/Ca; planktonic foraminifera; sample size; single test; Sr/Ca; geochemistry : major and trace element geochemistry; oceanography : biological and chemical :; trace elements (0489)

Funding

  1. Natural Environment Research Council [NE/C510583/1] Funding Source: researchfish

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The variability in Mg/Ca and Sr/Ca within individual tests and chambers of tests, and samples consisting of differing numbers of individuals, was determined for Globigerina bulloides and Globorotalia truncatulinoides in a North Atlantic core top sample (52.918 degrees N 16.917 degrees W'). The variability in Mg/Ca and Sr/Ca within individual tests and chambers was determined by electron microprobe, and samples consisting of variable sample size were measured using inductively coupled plasma optical emission spectrometer (ICP-OES). Large compositional heterogeneity was found within individual chambers, and within the test as a whole, of the two species and the presence of regions with up to similar to 10 mmol/mol Mg/Ca, especially in G. bulloides. Mean Mg/Ca decreases in successive chambers of G. bulloides (especially the 300-355 mu m fraction) and is accompanied by decreasing variance but is not statistical significant. Sr/Ca is much more homogeneously distributed, with a normal distribution, and shows no differences from chamber to chamber. The variability of Mg/Ca and Sr/Ca decreases with increasing sample size, from single to five to twenty tests per sample, approximately as for a normal distribution, with greater variability for G. bulloides than for G. truncatulinoides, equivalent to uncertainties in temperature (n = 20) of 1.1 degrees C and 0.7 degrees C for the two species within the whole of the sediment mixed layer.

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