Journal
ORGANIC LETTERS
Volume 7, Issue 24, Pages 5485-5487Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol052490b
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Two flexible receptors for carboxylic acids, based on 1-amino-3-fluoro-2-alcohol functional arrays and built on aminomethylpyridine platforms, are described. The C(2)-symmetric one [from 2,6-bis(aminomethyl)pyridine] has been shown to be an efficient CSA due to its ability to form geometrically different diastereomeric complexes enabling the discrimination between the enantiomers of a series of carboxylic acid in the (1)H NMR spectra.
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