4.8 Article

Highly selective two-photon chemosensors for fluoride derived from organic boranes

Journal

ORGANIC LETTERS
Volume 7, Issue 24, Pages 5481-5484

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol052323b

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Three organoboron compounds are shown to be two-photon fluorescent sensors for fluoride anion with high sensitivity and selectivity. The recognition mechanism is attributed to the unique steric structure of the bulky dimesitylboryl group and the Lewis acid-base interaction between trivalent boron atom and fluoride anion.

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