Journal
ORGANIC LETTERS
Volume 7, Issue 24, Pages 5433-5436Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol052139q
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A practical and general two-step synthesis of carbamate-protected (E)-vinylglycines from aliphatic aldehydes is reported. The key step involves the kinetic alpha-protonation of dianionic dienolates derived from dehydroamino acids.
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