Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 70, Issue 24, Pages 10132-10134Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo0516178
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- NCRR NIH HHS [P20 RR-016470] Funding Source: Medline
- NIGMS NIH HHS [GM 08216] Funding Source: Medline
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Aromatic O-triisopropylsilyl ketoximes were efficiently rearranged to cyclic and acyclic aniline derivatives on reduction with BF3-ethearate/borane. The bulk of the substituents on the silicon atom, the size of the aliphatic ring, and the presence of alkoxy substituents on the aryl group all play an important role in the aniline.
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