Journal
MOLECULES
Volume 10, Issue 12, Pages 1446-1457Publisher
MDPI
DOI: 10.3390/10121446
Keywords
duocarmycin; free-radicals; intramolecular cyclization; indole; pyrroloquinoline
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Aryl free-radicals generated at the C-7 position of ethyl indole-2-carboxylates bearing N-allyl and propargylic groups triggered intramolecular cyclizations to furnish a new class of Duocarmycin analogues, formal ethyl pyrrolo[3,2,1-ij]quinoline-2carboxylate derivatives, through the less favorable 6-endo-trig cyclization mode.
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