Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 690, Issue 24-25, Pages 5441-5450Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2005.07.092
Keywords
carbene transfer; homogeneous catalysis; copper; silver; gold; trispyrazolylborate; N-heterocyclic carbenes; cyclopropanation; C-H functionalization
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Two families of catalysts containing trispyrazolylborate (Tp(x)) or N-heterocyclic carbenes (NHC) with the group 11 metals have proven useful for several reactions involving the transfer of the :CHCO2Et group from ethyl diazoacetate to saturated and unsaturated substrates. (c) 2005 Elsevier B.V. All rights reserved.
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