The composition and size distribution of the dust in the coma of Comet Hale-Bopp

We discuss the composition and size distribution of the dust in the coma of Comet Hale-Bopp. We do this using a model fit for the infrared emission measured by the Infrared Space Observatory (ISO) and the measured degree of linear polarization of scattered light at various phase angles and wavelengths. The effects of particle shape on the modeled optical properties of the dust grains are taken into account. Both the short wavelength (7-44 mu m) and the long wavelength (44-120 mu m) infrared spectrum are fitted using the same dust parameters, as well as the degree of linear polarization at twelve different wavelengths in the optical to near-infrared domains. We constrain our fit by forcing the abundances of the major rock forming chemical elements to be equal to those observed in meteorites. The infrared spectrum at long wavelengths reveals that large grains are needed in order to fit the spectral slope. The size and shape distribution we employ allows us to estimate the sizes of the crystalline silicates. The ratios of the strength of various forsterite features show that the crystalline silicate grains in Hale-Bopp must be submicrometer-sized. On the basis of our analysis the presence of large crystalline silicate grains in the coma can be excluded. Because of this lack of large crystalline grains combined with the fact that we do need large amorphous grains to fit the emission spectrum at long wavelengths, we need only approximately 4% of crystalline silicates by mass (forsterite and enstatite) to reproduce the observed spectral features. After correcting for possible hidden crystalline material included in large amorphous grains, our best estimate of the total mass fraction of crystalline material is similar to 7.5%, which is significantly lower than deduced in previous studies in which the typical derived crystallinity is similar to 20-30%. The implications of this low abundance of crystalline material on the possible origin and evolution of the comet are discussed. We conclude that the crystallinity we observe in Hale-Bopp is consistent with the production of crystalline silicates in the inner Solar System by thermal annealing and subsequent radial mixing to the comet forming region (similar to 30 AU). (c) 2005 Elsevier Inc. All rights reserved.