4.1 Article Proceedings Paper

Carbonatites and carbonatites and carbonatites

Journal

CANADIAN MINERALOGIST
Volume 43, Issue -, Pages 2049-2068

Publisher

MINERALOGICAL ASSOC CANADA
DOI: 10.2113/gscanmin.43.6.2049

Keywords

carbonatite; melilitite; nephelinite; ijolite; melilitolite; aillikite; nepheline syenite; liquid immiscibility; carbothemial residue; upper mantle

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Carbonatites are redefined using a mineralogical-genetic classification and divided into two groups: primary carbonatites, and carbothermal residua. Attention is drawn to the fact that carbonatite is both a petrographic term applicable to a particular rock-type as well as a group name applied to complex of related carbonate and silicate rocks in a magmatic or extrusive, complex. Primary carbonatites, in terms of mineralogical-genetic classifications, rather than simple modal classifications. can be divided into it group of bona fide magmatic carbonatites formed from diverse mantle-derived magmas. i.e.. carbonatites associated with the melilitite, nephelinite. aillikite and kimberlite clans, with the latter best being termed calcite kimberlites. Each magma type and associated carbonatites are considered to be genetically, distinct. and formed at different depths in the upper mantle by different degrees of partial melting. Carbonatites associated with the melilitite and nephelinite clans can have a multiplicity of origins, and may be formed by fractional melting, fractional crystallization or liquid immiscibility. Calcite kimberlites are small-volume late-forming differentiates that are not related to other carbonatites or their parental magmas. The origin and genetic relationships of the Oldoinyo Lengai natrocarbonatite cannot be unambiguously determined. although these rocks are regarded its it distinct variety of primary carbonatite. Carbonate-rich rocks associated with diverse potassic or sodic peralkaline saturated to undersaturated magmas derived predominantly from metasomatized lithospheric mantle, together with REE-carbonate-rich rocks Of Undetermined genesis. are best termed carbothermal residua rather than carbonatite. There call be mineralogical (or modal) convergence between these rocks and low-pressure REE-rich derivatives of bona fide primary carbonatites. Carbonate-rich rocks formed by pneumatolytic reactions or anatectic melting of crustal rocks should not be considered to be carbonatites.

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