Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 690, Issue 24-25, Pages 5849-5855Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2005.07.085
Keywords
tetrahydropyrimidin-2-ylidene; N-heterocyclic carbene; arylation; rhodium
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Six new rho dium-tetrahydropyrimidin-2-ylidene complexes (2a-f) have been prepared and characterized by C, H, N analysis, H-1 NMR and C-13 NMR. Phenylboronic acid reacts with aldehydes in the presence of a catalytic amount of the new rhodium(l)-carbene complexes, RhCl(COD)(1,3-dialkyl-3,4,5,6-tetrahydropyrimidin-2-ylidene), (2a-f), to give the corresponding secondary aryl alcohols in good yields (72-96%). (c) 2005 Elsevier B.V. All rights reserved.
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