Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 347, Issue 15, Pages 1933-1936Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200505259
Keywords
asymmetric catalysis; kinetic resolution; Schiff bases; sulfoxides; vanadium
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Simple, inexpensive, preformed vanadium-Schiff base complexes were facilely prepared and used in enantioselective sulfoxidation. Both the amount of aqueous H2O2 and reaction time greatly influenced the ee values and yields of chiral sulfoxides. High enantioselectivities (up to 99% ee) and reasonable yields (> 40%) for various chiral sulfoxides were achieved by combining enantioselective sulfoxidation and appropriate concomitant kinetic resolution.
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