Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 690, Issue 24-25, Pages 6233-6237Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2005.09.038
Keywords
hydroformylation; NHC/rhodium catalysts; steric/electronic effects
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We present an over-view of eight different rhodium-N-heterocyclic carbene (NHC) complexes 1-8 and their catalytic activity and selectivity in hydroformylation of I-octene. It could be shown that activity can be increased by going from electron-rich NHC to electronpoor NHC-ligands. However, no increase in the selectivity could be achieved by introducing bulky substituents to the NHCs. (c) 2005 Elsevier B.V. All rights reserved.
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