Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 26, Issue 23, Pages 1829-1834Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200500554
Keywords
atom transfer radical polymerization (ATRP); graft polymerization; poly(glycidyl methacrylate) (PGMA); polymer brushes; polystyrene (PS)
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This contribution describes the graft polymerization of polystyrene (PS) by atom transfer radical polymerization at 50, 60, and 75 degrees C. Thick PS brushes were grown from initiator-functionalized PGMA layers on silicon, and constant growth rates provide indirect evidence that the polymerizations were controlled.
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