4.7 Article

Quantum escape kinetics over a fluctuating barrier

Journal

JOURNAL OF CHEMICAL PHYSICS
Volume 123, Issue 22, Pages -

Publisher

AMER INST PHYSICS
DOI: 10.1063/1.2135781

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The escape rate of a particle over a fluctuating barrier in a double-well potential exhibits resonance at an optimum value of correlation time of fluctuation. This has been shown to be important in several variants of kinetic model of chemical reactions. We extend the analysis of this phenomenon of resonant activation to quantum domain to show how quantization significantly enhances resonant activation at low temperature due to tunneling. (c) 2005 American Institute of Physics.

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