Journal
ORGANIC LETTERS
Volume 7, Issue 25, Pages 5613-5616Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0522992
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[GRAPHICS] Incorporation of hydrophilic tetraarylporphyrin phosphoramidites into the 5'-termimus of the DNA as well as noncharged porphyrin-DNA interactions have been studied. Porphyrin-modified oligonucleotides show lower melting temperatures than their unmodified analogues. Single-stranded DNA interacts more strongly with porphyrin and causes more intense chiral disturbance in the porphyrin environment than the corresponding double strand.
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