Journal
TETRAHEDRON LETTERS
Volume 46, Issue 51, Pages 8837-8839Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2005.10.094
Keywords
oxiranes; benzeneselenol; beta-hydroxy selenides; beta-cyclodextrin; supramolecular water
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A simple and efficient method for the synthesis of beta-hydroxy selenides is reported at room temperature in impressive yields for the first time by the highly the regioselective ring-opening of oxiranes with benzeneselenol in water under supramolecular catalysis in the presence of beta-cyclodextrin. This is a direct one-pot synthesis of beta-hydroxy selenides under mild conditions using water as solvent and has many advantages over the existing methodologies. beta-Cyclodextrin can also be recovered and reused. (c) 2005 Elsevier Ltd. All rights reserved.
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