Journal
SURFACE & COATINGS TECHNOLOGY
Volume 200, Issue 7, Pages 2223-2227Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.surfcoat.2004.07.125
Keywords
electroplating; amorphous coating; barrier coating; interdiffusion coefficients; nickel ion release
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By using citrate as the complexing agent, cobalt-molybdenum-phosphorus (Co-Mo-P) alloy coatings were successfully developed and electrodeposited. Coatings containing up to about 10% Mo have been produced. Coating containing 8% Mo, 20% phosphorus and Co balance have been investigated further as barrier coating. To study the diffusion property, the apparent interdiffusion coefficients of Cu/CoMo-P/Ni were determinated. The micro-profiling and Boltzmarm-Matano Method were used to obtain the interdiffusion coefficients. It was found that the interdiffusion coefficients for nickel are higher than that the apparent interdifflision coefficients of the Cu/Co-Mo-P alloys. The results have indicated the potentials of Co-Mo-P alloy as effective substitutes for nickel. (c) 2004 Elsevier B.V All rights reserved.
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