4.8 Article

Meso-structure formation for enhanced organic photovoltaic cells

Journal

ORGANIC LETTERS
Volume 7, Issue 26, Pages 5749-5752

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol051950y

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Formation of a controlled fullerene mesophase within an organic host system has enabled us to create high-power conversion efficiency photovoltaics. This mesophase is formed using thermal gradients that provide a fluidic mobility of the fullerenes allowing for greater dispersion of nanocrystalline 1-(3-methoxycarbonyl)propyl-1-phenyl-(6,6)C-61 (PCBM) within regioregular poly(3-hexylthiophene) (P3HT). From this reorganization of the component materials in the matrix the overall efficiency of the system jumps dramatically from the roughly 2.4% to 5.2%.

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