Journal
ORGANIC LETTERS
Volume 7, Issue 26, Pages 5781-5783Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol052291s
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Catalytic [2 + 2 + 1 + 1] cocyclization reaction of an alkyne, an alkene, and two molecules of carbon monoxide, leading to functionalized hydroquinones, was studied. Using [Cp*RuCl2](2) as a catalyst, we found that a variety of electron-deficient alkenes, such as alpha,beta-unsaturated ketones, esters, amides, and nitriles, can be employed as an alkene coupling partner to give the corresponding hydroquinones.
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