Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 27, Issue 1, Pages 63-68Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200500601
Keywords
aniline oligomers; diblock oligomers; oxidation state; ring-opening polymerization; surface morphology; TEM
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Tetraaniline-block-poly(L-lactide) diblock oligomers are synthesized via ring-opening polymerization. The diblock oligomers cast from all L-lactide selective solvent (chloroform) show spherical aggregates for the leucoemeraldine state, and ring-like structures that are composed of much smaller spherical aggregates for the emeraldine state. The formation mechanisms of the two different surface morphologies are discussed in detail.
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