Journal
APPLIED CATALYSIS A-GENERAL
Volume 298, Issue -, Pages 109-114Publisher
ELSEVIER
DOI: 10.1016/j.apcata.2005.09.027
Keywords
cobalt oxide; ozone decomposition; CO oxidation; VOCs complete oxidation
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An alumina-supported cobalt oxide system with overstoichiometric oxygen (CoOx/Al2O3) was investigated with respect to heterogeneous catalytic decomposition of ozone, complete oxidation of volatile organic compounds (VOCs) and oxidation of CO. The experiments were performed in the temperature range of -45 to 250 'C in an isothermal plug-flow reactor. The characterization of the CoOx/Al2O3 catalyst was performed by chemical analysis, XPS, XRD, IR techniques, magnetic and adsorption measurements. A very high activity of the catalyst towards ozone decomposition was observed even at temperatures below -40 degrees C, the catalyst remaining active for a long time. The activity of the catalyst with respect to complete oxidation of VOCs and oxidation of carbon monoxide was studied in presence of different oxidizing agents (ozone or oxygen). A significant increase in the catalytic activity and decrease in the reaction temperature was observed using ozone as an oxidant. Two main reasons for this behaviour were found: (i) the high content of active and mobile oxygen obtained during the synthesis on the catalyst surface; (ii) the catalytically active complex of O-[Co4+], formed during the reaction of ozone decomposition and able to oxidize VOCs at room temperature. (c) 2005 Elsevier B.V. All rights reserved.
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