Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 110, Issue 1, Pages 25-29Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp055692y
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Selective oxidation of single-wall carbon nanotubes (SWCNTs) by H2O2 was conducted at varying heating times and monitored by UV-vis-NIR spectroscopy. A major increase in the relative absorption intensity indicated a higher than 80% concentration of metallic SWCNTs in the final product. Here, it is suggested that semiconducting SWCNTs are more reactive than metallic SWCNTs because of hole-doping by H2O2, resulting in faster oxidation.
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