4.4 Article

A concise method for synthesis of diaryl aryl- or alkylphosphonates

Journal

TETRAHEDRON LETTERS
Volume 47, Issue 3, Pages 277-281

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2005.11.028

Keywords

triaryl phosphite; triethyl phosphite; diaryl arylphosphonate; diaryl alkylphosphonate; Arbuzov reaction

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A convenient method has been developed to synthesize diaryl arylphosphonates from triaryl phosphites, triethyl phosphite, and aromatic halides. The new method relies on the triethyl phosphite assisted nickel catalyzed Arbuzov reaction and can be applied to synthesize certain diaryl alkylphosphonates without catalysts. (c) 2005 Elsevier Ltd. All rights reserved.

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