Journal
ORGANIC LETTERS
Volume 8, Issue 2, Pages 289-292Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol052610f
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Only 1-3 mol % of PtCl(2) or AuBr(3) was sufficient to promote generation and [3+2] cycloaddition of transition-metal-containing azomethine ylides derived from M(o-alkynylphenyl)imines bearing an internal alkyne moiety. A highly efficient method for the preparation of synthetically useful tricyclic indole derivatives having a substituent at the 3-position of the indole nucleus was established by this method.
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