Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 3, Pages 341-343Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b512312g
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A spin-bearing bis-bidentate ligand, designed from a pyrimidyl-substituted R-CN2S2 neutral radical, is used to co-ordinate two Mn(II) metal centres yielding a thermally stable complex with antiferromagnetic coupling between the ligand-centred spin and the metal-centred spins, and thus an overall ferrimagnetic coupling scheme with a ground state S = 9/2.
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