Microporous aluminum bisphosphonates

Several bisphosphonates of trivalent elements (Al, Ga and La) have been prepared under different synthetic conditions in order to induce microporosity. Two bisphosphonic acids, 4,4'-biphenylenebis(phospholiie acid), [H2O3P C6H4](2), and 4-(4-phosphonophenoxy)phenyl phosphonic acid, [H2O3P-C6H4](2)-O, have been used as crosslinking agents. The materials have been characterized by a number of techniques including N-2 adsorption-desorption isotherms and temperature-programmed desorption of ammonia to characterize the specific surface and acid properties, respectively. Crosslinked hybrid materials with surface areas ranging between 100 and 400 m(2)/g and textural properties varying from non-porous to mainly microporous can be isolated. The use of inexpensive phenylphosphonic acid as a spacer group has also been studied. The experimental conditions to get microporous solids with specific surface areas as high as 400 m(2)/g are described. Usually, the compounds contain both mesopores and micropores. The micropore size distributions are centered between 7 and 20 angstrom. (c) 2005 Elsevier Inc. All rights reserved.